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Statistical Thermodynamics - Spring 2023


(See also: Statistical Thermodynamics - Spring 2021)
Material covered:

(Syllabus)

Week Monday Wednesday
Jan 23 No classes Methods of Thermodynamics and Statistical Physics. Definitions of thermodynamics. Temperature. Equation of state.
Jan 30 Thermodynamic coefficients. Work. Internal energy. First law of thermodynamics. Heat. Heat capacity. Mayer's equation. The adiabatic equation. Heat machines. Carnot cycle.
Feb 6 Entropy at equilibrium. Thermodynamic potentials. Thermodynamic relations. Entropy of the ideal gas. Adiabatic thermodynamic coefficients. Third law of thermodynamics. Systems with variable mass, chemical potential. Problem solving
Feb 13 Lincoln birthday, no classes Second law of thermodynamics. Carnot's theorem.  Entropy increase in irreversible processes.
Feb 20 Presidents Day, no classes Molecular theory of the ideal gas. Basic assumptions. Characteristic lengths. Velocity and speed distribution function. Molecular flux. Pressure due to molecular impact.
Feb 27 Relation between temperature and average kinetic energy. Heat capacity of the ideal gas. Degrees of freedom. Maxwell-Boltzmann disctribution. Characteristic speeds of molecules. Problem solving
Mar 6 Midterm test 1 Statistical physics. Classical vs. quantum approaches. Quantum states and equidistribution assumption. Combinatorics and thermodynamic probability. Coin tossing experiment. Stirling formula. Combinatorics of multistate particles.
Mar 13 Thermodynamic probability and entropy. Boltzmann statistics. Relation between statistical parameters and thermodynamic quantities. Formalism of quantum mechanics. Eigenvalue problems for matrices and differential operators. Stationary Schrödinger equation. Particle in a rigid box. Degeneracy. Density of states.
Mar 20 Statistical thermodynamics of the ideal gas Statistical mechanics of harmonic oscillators
Mar 27 Average quantum number of the harmonic oscillator as a particular case of the Bose-Einstein distribution. Statistical mechanics of rotators. Solid as a collection of harmonic oscillators. Sound waves in a box. Phonons. Density of states. Heat capacity of solids. Debye theory.
Apr 3 Spins in magnetic field. Energy levels and partition function. Brillouin function, heat capacity, and magnetic susceptibility. Spring Recess
Apr 10 Spring Recess Spring Recess
Apr 17 Spins in magnetic field. Phase transitions and mean-field approximation. One-dimensional Ising model
Apr 24 Grand canonical ensemble for systems of indistinguishable particles and systems with interaction. Spin and statistics. Bosons and fermions. Statistics of noninteracting indistinguishable particles.
May 1 Bose condensation. Energy, heat capacity, and pressure of the Bose gas. Fermi gas at zero temperature. Degenerate Fermi gas at nonzero temperatures. Heat capacity of the degenerate Fermi gas
May 8 Electromagnetic radiation (photon gas) Problem solving
May 15 Midterm test 2 No classes

 
Problem sets:
Problems 01 02 03 04 05
Solutions 01 02 03 04 05

   
Textbook